INGENIA

MAT-05

Lever rule

Wα = (Cβ − C0)/(Cβ − Cα) for a two-phase alloy.

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Phase diagramsGibbs phase rule

Governing equation

Wα=CβC0CβCα,Wβ=1WαW_\alpha=\dfrac{C_\beta-C_0}{C_\beta-C_\alpha},\quad W_\beta=1-W_\alpha

where

C_0
Alloy composition (wt%)
C_\alpha
α composition (wt%)
C_\beta
β composition (wt%)
W_\alpha
α fraction ()
W_\beta
β fraction ()

Lecture brief

Historical brief

Hooke (1678), Hall–Petch grain size, Arrhenius activation and Paris fatigue-crack growth are the spine of materials selection. The sheets relate stress, microstructure and life. This sheet (MAT-05 — Lever rule) is the form associated with Gibbs phase rule. Working symbols: C0C_0, CαC_\alpha, CβC_\beta \rightarrow WαW_\alpha, WβW_\beta. Mass conservation on a tie-line of a binary phase diagram is a mechanical lever: the phase fractions are inverse length ratios.

Purpose

Purpose: compute WαW_\alpha, WβW_\beta from C0C_0, CαC_\alpha, CβC_\beta in Materials via Wα=CβC0CβCα,Wβ=1WαW_\alpha=\dfrac{C_\beta-C_0}{C_\beta-C_\alpha},\quad W_\beta=1-W_\alpha Wα = (Cβ − C0)/(Cβ − Cα) for a two-phase alloy. Use it when a real materials question must be answered in SI before a code check.

Live realistic example

In symbols

Live case. Given C_0 = 40.000\,\mathrm{wt%}, C_\alpha = 10.000\,\mathrm{wt%}, C_\beta = 80.000\,\mathrm{wt%}, the governing relation Wα=CβC0CβCα,Wβ=1WαW_\alpha=\dfrac{C_\beta-C_0}{C_\beta-C_\alpha},\quad W_\beta=1-W_\alpha yields Wα=0.571W_\alpha = 0.571\,\mathrm{—}, Wβ=0.429W_\beta = 0.429\,\mathrm{—}. Binary isomorphous or eutectic tie-line, mass %. Move a slider: the numbers are this situation, not a canned story.

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Inputs

Outputs

  • α fraction W_\alpha0.571
  • β fraction W_\beta0.429
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MAT-05 · phase
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Narration of this film

Binary isomorphous or eutectic tie-line, mass %.

Mass conservation on a tie-line of a binary phase diagram is a mechanical lever: the phase fractions are inverse length ratios.

Reading speed

Watch on YouTube